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426 If the heat of combustion of urea, (NH2)2CO(s),at 29815 K (25 C) is 631 660 J mol-' when the products are C02(g), H20(1), and N2(g), what is AH&* for urea at 29815 K (25"C) 427 The higher heating value (HHV) of a fuel is its standard heat of combustion at 29815 K (25 C) with liquid water as a product; the lower heating value (LHV) is for water vapor as product (a) Explain the origins of these terms (b) Determine the HHV and the LHV for natural gas, modeled as pure methane ( c ) Determine the HHV and the LHV for a home-heating oil, modeled as pure liquid n-decane For n-decane as a liquid A H;298= -249 700 J mol-' 428 A light fuel oil with an average chemical composition of CloHlsis burned with oxygen in a bomb calorimeter The heat evolved is measured as 43 960 J g-' for the reaction at 29815 K (25 C) Calculate the standard heat of combustion of the fuel oil at 29815 K (25 C) with H20(g)and C02(g) as products Note that the reaction in the bomb occurs at constant volume, produces liquid water as a product, and goes to completion 429 Methane gas is burned completely with 30% excess air at approximately atmospheric pressure Both the methane and the air enter the furnace at 30315 K (30 C) saturated with water vapor, and the flue gases leave the furnace at 177315 K (1500 C) The flue gases then pass through a heat exchanger from which they emerge at 32315 K (50 C) Per mole of methane, how much heat is lost from the furnace, and how much heat is transferred in the heat exchanger 430 Ammonia gas enters the reactor of a nitric acid plant mixed with 30% more dry air than is required for the complete conversion of the ammonia to nitric oxide and water vapor If the gases enter the reactor at 34815 K (75"C), if conversion is 80%, if no side reactions occur, and if the reactor operates adiabatically, what is the temperature of the gases leaving the reactor Assume ideal gases 431 Ethylene gas and steam at 59315 K (320 C) and atmospheric pressure are fed to a reaction process as an equimolar mixture The process produces ethanol by the reaction:.

The liquid ethanol exits the process at 29815 K (25 C) What is the heat transfer associated with this overall process per mole of ethanol produced

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Laser printers are like specialized photocopiers Using the digital image in the computer s memory as a template, they electrically charge a piece of paper The printer then allows toner a fine ink-like powder to come into contact with the paper (See Figure 15-1 for a look at a typical toner cartridge) The toner sticks to the paper in places where it has an electrostatic charge, and the toner is finally permanently melted into the paper by a very hot fusing wire Laser printers have a lot of advantages They can print quickly (many personal laser printers can generate as many as eight or ten pages per minute), and the toner lasts a long time, yielding a very low cost per page My Hewlett-Packard (HP) LaserJet 6P, which has served me reliably for many years now, prints about 3,000 to 5,000 sheets of paper for each $80 toner cartridge Those advantages add up to a good all-around office printer that handles most common print jobs pretty well Personal laser printers can be purchased for between $200 and $500 Unfortunately, laser printers tend to be better at printing text than graphics That s mainly because most laser printers are black-and-white devices, able to generate just shades of gray Color laser printers are available, but since they tend to cost more than $1,000, they re beyond the reach of most people Even if you could purchase a color laser printer, I wouldn t recommend it for printing digital images for framing Color laser printers tend to produce shiny, artificiallooking prints, and they limit you to a print size of 8 10 inches Laser printers can certainly be used to print images, and they can do it well, as long as your needs don t include color You can print a large quantity of family newsletters with a laser printer faster than with an inkjet, for instance.

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432 A gas mixture of methane and steam at atmospheric pressure and 77315 K (500 C) is fed to a reactor, where the following reactions occur:

The product stream leaves the reactor at 112315 K (850 C) Its composition (mole fractions) is:

When you use a function in your source code, the function acts a little like a variable; all the text of the function call, from the start of its name to the end of its closing parenthesis, could be replaced by a variable that contained the same resulting data. Function calls cannot appear on the lefthand side of an assignment statement, but they can appear almost anywhere else that a variable can appear. For example, the following two lines could be used to replace line 02 in the sample:

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